Researchers from China have observed record-breaking in-plane optical anisotropy in a van der Waals crystal
In general, when you measure material properties such as optical permittivity, your measurement doesn’t depend on the direction in which you make it.
However, recent research has shown that this is not the case for all materials. In some cases, their optical permittivity is directional. This is commonly known as in-plane optical anisotropy. A larger difference between optical permittivity in different directions means a larger anisotropy.
Materials with very large anisotropies have applications in a wide range of fields from photonics and electronics to medical imaging. However, for most materials remains available today, the value remains relatively low.
These potential applications combined with the current limitation has driven a large amount of research into novel anisotropic materials.
In this latest work, a team of researchers studied the quasi-one-dimensional van der Waals crystal: Ta2NiSe5.
Van der Waals (vdW) crystals are made up of chains, ribbons, or layers of atoms that stick together through weak van der Waals forces.
In quasi-one-dimensional vdW crystals, the atoms are strongly connected along one direction, while the connections in the other directions are much weaker, making their properties very direction-dependent.
This structure makes quasi-one-dimensional vdW crystals a good place to search for large optical anisotropy values. The researchers studied the new crystal by using a range of measurement techniques such as ellipsometry and spectroscopy as well as state of the art first principles computer simulations.
The results show that Ta2NiSe5 has a record-breaking in-plane optical anisotropy across the visible to infrared spectral region, representing the highest value reported among van der Waals materials to date.
The study therefore has large implications for next-generation devices in photonics and beyond.
